黔北镇远牛蹄塘组黑色页岩沉积环境与有机质富集关系   总被引：1，自引：0，他引：1  

夏鹏  付勇  杨镇  郭川  黄金强  黄明勇 《地质学报》2020,94(3):947-956

通过矿物组分、主量元素、微量元素、碳氧同位素等特征，分析了黔北地区镇远县ZX井牛蹄塘组黑色页岩的岩相类型和不同岩相页岩的沉积环境及其与有机质富集间的关系。结果表明，牛蹄塘组下段以硅质页岩为主，TOC含量4. 96%~10. 10%；上段以富泥硅质页岩为主，TOC含量1. 43%~9. 04%。下段硅质页岩沉积于水流停滞的深水陆棚环境，沉积古水体为贫氧的还原状态；上段富泥硅质页岩沉积时期，仍为贫氧的还原环境，但水体滞留程度、还原性较下段硅质页岩沉积期弱。贫氧的还原环境是影响牛蹄塘组黑色页岩有机质富集的主要因素，热液作用和陆源碎屑对牛蹄塘组黑色页岩有机质富集的影响较小。  相似文献   

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

微生物勘探技术在潮汕坳陷油气勘探中的应用初探     

赵忠泉  孙鸣  万晓明  陈胜红  赵静  宋立军  李辉  强昆生  梁永兴 《中国地质》2020,47(3):645-654

东沙海域潮汕坳陷中生界研究程度相对较低,油气分布规律不明,为了加强对该区油气分布和富集规律的研究,针对潮汕坳陷西部地质目标首次应用微生物地球化学勘探技术(MGCE),探讨其含油气性。MGCE技术以轻烃微渗漏理论为基础,采用地质微生物学方法和地球化学方法检测研究区海底表层的微生物异常和吸附烃异常,预测研究区下伏地层中油气的富集区及其油气性质。检测结果显示研究区西部凹陷的斜坡区微生物异常呈块状发育,轻烃微渗漏强度变化大,可能为潜在油气富集区,酸解吸附烃成果显示可能的油气性质为干气和凝析油气。  相似文献   

Relationship Between Electrical Properties and Sedimentary Environment of the Longmaxi Formation Shale, Southern Sichuan     

YANG Kai  ZHANG Bing  WANG Xuben  HE Lanfang  YANG Hongyu  WANG Pengwan  TANG Jialin  DENG Jixin  ZHANG Cong 《《地质学报》英文版》2020,94(5):1531-1546

The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献   

华南上扬子区深部温度估算及其油气地质意义     

李香兰  刘绍文  徐明  李旭东  郝春艳 《地质学报》2020,94(6):1896-1910

盆地热体制及深部温度估算对油气和区域地热能资源评估具有重要意义。南方上扬子区是海相油气勘探的重要区块,近年来更是我国页岩气勘探的主要选区。然而,由于数据不足及研究目标的分散,该区的盆地热体制特征还有待深化。结合前人已有地热数据,并整合新近开展的稳态测温数据,我们揭示了上扬子区现今地温梯度、大地热流分布特征,继而估算了1000～6000m埋深处的深部地层温度和2套主要古生界海相烃源岩底界面处的温度。结果表明,上扬子区具有中-低温的地热状态,其现今地温梯度和大地热流的范围(平均值)分别为10～74℃/km(24℃/km)和27～118mW/m~2(64mW/m~2),整体上从东北向西南方向递增,呈现出"东北低、西南高"的分布趋势。1000～6000m埋深处估算温度的分布格局与地温梯度及热流的分布趋势基本一致。东北部的鄂西-湘北地区为低温区,中部的四川盆地其大部分为中温区,西南的云南地区为高温区。上扬子区现今地热分布格局受区域差异构造和岩浆作用控制。结合储层温度估算并综合其他油气地质资料,提出川东的石柱-涪陵、川南的威远-自贡-泸州和宜宾-长宁等区的下志留统龙马溪组页岩层系是上扬子区油气勘探有利区带。  相似文献   

Geochemical characteristics and sedimentary environment of the Middle Devonian organic-rich shales in the Northwest of Guizhong Depression,Southwest China     

《China Geology》2020,3(4):567-574

In order to figure out the redox conditions and paleo-sedimentary environment of the Middle Devonian shales in the northwest of Guizhong Depression, the trace element analysis was conducted on the Middle Devonian cores (320.35–938.50 m) of the typical shale gas investigation well (GY-1) at a 1.50 m sampling interval through X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). According to the test result, the average values of V/(V+Ni), V/Cr and Ni/Co in Nabiao formation (Fm.) are larger than 0.67, 4.65 and 7.71 respectively, and Nabiao Fm. is rich in biological assemblages such as tabasheer, ammonite, etc. These evidences indicate the rising sea level rose relatively in the sedimentation period of Nabiao Fm. and a deepwater shelf environment, which was favorable for the preservation of organic matters. The V/(V+Ni), V/Cr and Ni/Co in Luofu Fm. and Tangting Fm. are 0.38–0.65, 0.73–4.10 and 3.70–6.72 respectively, indicating that the sea level dropped relatively in their sedimentation period, during which the water bodies became shallow, and the sedimentary environment was a weak oxidizing shallow water shelf environment. In addition, the variation of TOC has a high correlation with the enrichment degree of Ba element, indicating the favorable conditions for the enrichment and preservation of organic matters under an oxygen-deficient environment. Moreover, according to the identification of trace element indexes, the northwest of Guizhong Depression experienced the sedimentary cycle of relative rise to relative fall of sea level from bottom to top in the Middle Devonian sedimentation period. The relative sea level rose to the highest in the sedimentation period of Nabiao Fm., in which the organic-rich shales with stable thickness and high organic content were deposited. Hence, the Nabiao Fm. could be regarded as the favorable exploration target interval in this area.  相似文献   

“一带一路”沿线国家石油资源流动类型演变     

孙琪  赵媛  张新林  夏四友 《世界地理研究》2020,29(2):337-345

综合运用石油自给率、流动比率等方法，以“一带一路”沿线国家为研究对象，对1995—2014年各国石油资源流动类型时空演变进行研究。结果表明：1）1995—2014年石油净补给型国家数量较为稳定，无产型或低产型国家的石油贸易倾向变化相对较小；基本自给型国家数量占比最大，1995年占比1/2，其余四个年份占比稳定在1/3；净支出型国家数量显著增加，至2014年其中有5个国家保持不变，表明这些国家的石油产量具有较大的优势。2）1995年和2014年汇地国家均为39个国家，其中有34个国家一直保持汇地职能，空间分布上呈东多西少，南多北少，东西分化以西亚、中亚、东欧为界；有14个国家一直保持源地职能，其空间分布格局与汇地相应，西多东少，南多北少，主要分布于西亚、东欧及中亚；交流地数量较少，呈分散分布，且分布地不稳定。3）从数量变化来看，研究期内汇地略有增加，源地略有减少，交流地略有增加；“一带一路”源地总出口量与汇地总进口量的比呈逐年降低趋势。  相似文献   

美国海上油气田租赁开发和环评体系研究          下载免费PDF全文

金嘉萌  黄必桂  安明明 《海洋开发与管理》2018,35(7):30-35

美国海洋油气环评贯穿于外大陆架油气区域租赁销售和开发的各个阶段。文章从美国外大陆架租赁范围界定入手,介绍油气区域租赁开发所经历的5年规划、区域销售、勘探和开发生产各阶段所涉及的环评文件类型。着重分析美国海洋油气开发环评体系、工作程序和文件内容,最后提出对我国海洋油气开发环评的启示,即:海洋油气规划环评在先;公众参与的早期介入;全过程政府环评;环评审查不等于排污许可。  相似文献   

海面溢油无人机高光谱遥感检测与厚度估算方法   总被引：2，自引：0，他引：2  

任广波  过杰  马毅  罗旭东 《海洋学报》2019,41(5):146-158

海上溢油是海洋国家所面临的共同问题，但至今仍没有一种可靠实用的海上溢油准确识别和油量遥感监测方法。为此，本文以无人机高光谱遥感为手段，开展了海面溢油检测与厚度估算方法研究。实验中，通过搭建室外大型水槽溢油实验装置，获取了模拟真实海洋环境条件下不同溢油量的遥感和现场光谱数据，在此基础上，分析并提取了海上溢油特征光谱波段，给出了海上溢油高光谱检测模型；针对现场实验条件下水面油膜厚度难以测定的问题，设计了3种利用总体溢油量的油膜厚度估算模型。得到如下主要结论:（1）675 nm和699 nm是海上溢油检测的有效特征波段，但对极薄的油膜没有检测能力；（2）提出了归一化溢油指数模型、反比例模型和吸收基线模型等3种海上溢油油膜厚度估算模型，其中对于薄油膜（厚度≤ 5 μm）和厚油膜（厚度>50 μm），反比例模型是溢油厚度反演的首选也是唯一选择。对于中厚度油膜，晴朗天气条件下，归一化溢油指数模型是油膜厚度反演的首选，同时反比例模型和溢油吸收基线模型也都有较好的反演能力，而在多云天气条件下，反比例模型效果最佳。  相似文献   

Responses of chemically active and naturally fractured shale under time‐dependent mechanical loading and ionic solution exposure          下载免费PDF全文

Chao Liu  Son K. Hoang  Younane N. Abousleiman 《国际地质力学数值与分析法杂志》2018,42(1):34-69

In this paper, the analytical dual‐porosity dual‐permeability poromechanics solution for saturated cylinders is extended to account for electrokinetic effects and material transverse isotropy, which simulate the responses of chemically active naturally fractured shale under time‐dependent mechanical loading and ionic solution exposure. The solution addresses the stresses, fracture pore pressure, matrix pore pressure, fluid fluxes, ion concentration evolution, and displacements due to the applied stress, pore pressure, and solute concentration difference between the sample and the circulation fluid. The presented solution will not only help validate numerical simulations but also assist in calibrating and interpreting laboratory results on dual‐porosity dual‐permeability shale. It is recommended that the analytical solutions of radial and axial displacements be used to match the corresponding laboratory‐recorded data to determine shale dual permeability and chemo‐electrical parameters including membrane coefficient, ions diffusion coefficients, and electro‐osmotic permeability.  相似文献